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These principles govern the chemical processes (metabolism) in all biological organisms. The First Law of Thermodynamics, also known as the law of conservation of energy, states that energy can neither be created nor destroyed. It may change from one form to another, but the energy in a closed system remains constant. 7.2: First Law of Thermodynamics. The First Law of Thermodynamics states that energy cannot be created or destroyed, only transformed. This can be demonstrated within a classic food web where light energy from the sun is harnessed as radiant energy by plants, converted into chemical energy, and stored as complex carbohydrates. The first law of thermodynamics in terms of enthalpy show us, why engineers use the enthalpy in thermodynamic cycles (e.g. Brayton cycle or Rankine cycle). The classical form of the law is the following equation: dU = dQ – dW. In this equation dW is equal to dW = pdV and is known as the boundary work. Boundary Work - pdV Work. Boundary work occurs because the.
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